Synthesis and Coordination Chemistry of Multidentate Phosphaalkene Ligands
Synthesis and Coordination Chemistry of Multidentate Phosphaalkene Ligands
| dc.contributor.advisor | Cain, Matthew F. | |
| dc.contributor.author | Nakashige, Mika Lyn | |
| dc.contributor.department | Chemistry | |
| dc.date.accessioned | 2021-07-29T23:15:00Z | |
| dc.date.available | 2021-07-29T23:15:00Z | |
| dc.date.issued | 2021 | |
| dc.description.degree | Ph.D. | |
| dc.identifier.uri | http://hdl.handle.net/10125/75917 | |
| dc.subject | Chemistry | |
| dc.title | Synthesis and Coordination Chemistry of Multidentate Phosphaalkene Ligands | |
| dc.type | Thesis | |
| dcterms.abstract | Phosphaalkenes (R’P=CHR) contain low-lying π* orbitals that can accept electron density, leading to the stabilization of electron-rich metal centers. In addition, phosphaalkenes are capable of undergoing redox-active/non-innocent processes, and we will explore if these properties can be exploited by constructing multidentate phosphaalkene-based ligands that create well-defined metal complexes with a single open and reactive coordination site. In the following chapters, we will discuss the coordination chemistry of new PN bidentate ligands, the synthesis of a PNP pincer, and the generation of sterically shielded Rh(I) and Ir(I) complexes supported by a tetradentate tris(phosphaalkene)phosphine ligand. | |
| dcterms.extent | 516 pages | |
| dcterms.language | en | |
| dcterms.publisher | University of Hawai'i at Manoa | |
| dcterms.rights | All UHM dissertations and theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner. | |
| dcterms.type | Text | |
| local.identifier.alturi | http://dissertations.umi.com/hawii:10930 |
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