New nickel complexes for trifluoromethylation studies

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dc.contributor.authorIchioka, Hiromi
dc.date.accessioned2016-02-19T22:10:03Z
dc.date.available2016-02-19T22:10:03Z
dc.date.issued2012-12
dc.description.abstractWe decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields.
dc.description.degreeM.S.
dc.identifier.urihttp://hdl.handle.net/10125/100881
dc.languageeng
dc.publisherUniversity of Hawaii at Manoa
dc.relationTheses for the degree of Master of Science (University of Hawaii at Manoa). Chemistry.
dc.subjectNickel
dc.subjecttrifluoromethylation
dc.titleNew nickel complexes for trifluoromethylation studies
dc.typeThesis
dc.type.dcmiText

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