New nickel complexes for trifluoromethylation studies
dc.contributor.author | Ichioka, Hiromi | |
dc.date.accessioned | 2016-02-19T22:10:03Z | |
dc.date.available | 2016-02-19T22:10:03Z | |
dc.date.issued | 2012-12 | |
dc.description.abstract | We decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields. | |
dc.description.degree | M.S. | |
dc.identifier.uri | http://hdl.handle.net/10125/100881 | |
dc.language | eng | |
dc.publisher | University of Hawaii at Manoa | |
dc.relation | Theses for the degree of Master of Science (University of Hawaii at Manoa). Chemistry. | |
dc.subject | Nickel | |
dc.subject | trifluoromethylation | |
dc.title | New nickel complexes for trifluoromethylation studies | |
dc.type | Thesis | |
dc.type.dcmi | Text |
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