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Part I, Tetrasubstituted allenyl ethers: Part Ii, Triply convergent cyclopentannelation

dc.contributor.authorTokeshi, Bradley K.
dc.date.accessioned2011-07-21T23:04:40Z
dc.date.available2011-07-21T23:04:40Z
dc.date.issued2006
dc.description.abstractPart I: A method for the synthesis of tetrasubstituted allene ethers is described. The Brook rearrangement is employed to form key propargyl ether intermediates. The resulting propargyl ethers are isomerized to allenes. The allenes are used in the cyclopentannelation reaction to form β, β-disubstituted cyclopentenones. Part II: Based on methodology developed by our group, the scope of the triply convergent cyc1openmnnelation is expanded. Modifications to the existing protocol are described. An expanded set of morpholino enamides are employed.
dc.description.degreeM.S.
dc.identifier.urihttp://hdl.handle.net/10125/20468
dc.languageeng
dc.publisherUniversity of Hawaii at Manoa
dc.relationTheses for the degree of Master of Science (University of Hawaii at Manoa). Chemistry; no. 4107
dc.rightsAll UHM dissertations and theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
dc.subjectEthers
dc.titlePart I, Tetrasubstituted allenyl ethers: Part Ii, Triply convergent cyclopentannelation
dc.typeThesis
dc.type.dcmiText

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