Phosphorus-Nitrogen Dative Pi Bond Character in O, N-Dimethylhydroxylaminohalophosphines and Related Compounds

Date
2014-01-15
Authors
Rosario, Marshal
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University of Hawaii at Manoa
Abstract
The chloro and fluorohalophosphines of O,N-dimethylhydroxylamine were prepared and characterized by NMR and mass spectral analyses. Some conclusions as to the dative π-character of the P-N bond are drawn from the 19F NMR temperature studies and from the localization of charge in the parent ions of the mass spectra.
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