The Far Infrared Absorbtion Spectrum of Trioctylamine Salts

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dc.contributor.author	Kludt, John
dc.date.accessioned	2014-01-15T20:18:24Z
dc.date.available	2014-01-15T20:18:24Z
dc.date.issued	2014-01-15
dc.identifier.uri	http://hdl.handle.net/10125/32161
dc.description.abstract	Far infrared studies of several salts of tri-n-octylamine have been conducted. Spectra were obtained for these salts in the solid state as well as in carbon tetrachloride and chloroform solutions. Two absorption bands were observed in the 100 cm-1 range. On the basis of a definite anion effect and the large degree of independence of these bands on the degree of aggregation, they were assigned to the stretching modes of the basic ion-pair. To explain the presence of two absorption bands it was proposed that besides the non-aliphatic hydrogen-bond between the cation and the anion these salts may also possess a cation-anion hy drogen-bond involving the lambda-methyl hydrogens.
dc.format.extent	vi, 49 pages
dc.publisher	University of Hawaii at Manoa
dc.rights	All UHM Honors Projects are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
dc.title	The Far Infrared Absorbtion Spectrum of Trioctylamine Salts
dc.type	Term Project
dc.type.dcmi	Text
dc.contributor.department	Chemistry
Appears in Collections:	Honors Projects for Chemistry

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