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New nickel complexes for trifluoromethylation studies

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Item Summary Ichioka, Hiromi 2016-02-19T22:10:03Z 2016-02-19T22:10:03Z 2012-12
dc.description M.S. University of Hawaii at Manoa 2012.
dc.description Includes bibliographical references.
dc.description.abstract We decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields.
dc.language.iso eng
dc.publisher [Honolulu] : [University of Hawaii at Manoa], [December 2012]
dc.relation Theses for the degree of Master of Science (University of Hawaii at Manoa). Chemistry.
dc.subject nickel
dc.subject trifluoromethylation
dc.title New nickel complexes for trifluoromethylation studies
dc.type Thesis
dc.type.dcmi Text
Appears in Collections: M.S. - Chemistry

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