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http://hdl.handle.net/10125/100881
New nickel complexes for trifluoromethylation studies
File | Description | Size | Format | ||
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Ichioka Hiromi r.pdf | Version for non-UH users. Copying/Printing is not permitted | 3.23 MB | Adobe PDF | View/Open | |
Ichioka Hiromi uh.pdf | Version for UH users | 3.24 MB | Adobe PDF | View/Open |
Item Summary
Title: | New nickel complexes for trifluoromethylation studies |
Authors: | Ichioka, Hiromi |
Keywords: | nickel trifluoromethylation |
Date Issued: | Dec 2012 |
Publisher: | [Honolulu] : [University of Hawaii at Manoa], [December 2012] |
Abstract: | We decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields. |
Description: | M.S. University of Hawaii at Manoa 2012. Includes bibliographical references. |
URI: | http://hdl.handle.net/10125/100881 |
Appears in Collections: |
M.S. - Chemistry |
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