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Solutions of Trioctylamine Sales

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Title: Solutions of Trioctylamine Sales
Authors: Sue, Alan
Issue Date: 15 Jan 2014
Publisher: University of Hawaii at Manoa
Abstract: Infrared studies of trioctylamine hydrochloride and trioctylamine perchlorate in l, 2-dichlorocthane and in benzene have been made. A tightly hydrogen-bonded ion-pair structure was found for the hydro­chloride, but for the perchlorate, anion-cation hydrogen-bonding does not seem to occur, though there is some kind of interaction present. On the addition of chloroform-d to the solutions, the amine hydro­chloride was still found as a tightly hydrogen-bonded ion-pair with vc little chloride-chloroform-d interaction occurring in comparison to that found in quaternary salts. No hydrogen bonding between the perchlorate anion and chloroform-d was found.
Pages/Duration: vii, 37 pages
Rights: All UHM Honors Projects are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
Appears in Collections:Honors Projects for Chemistry

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