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The Far Infrared Absorbtion Spectrum of Trioctylamine Salts

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Title: The Far Infrared Absorbtion Spectrum of Trioctylamine Salts
Authors: Kludt, John
Issue Date: 15 Jan 2014
Publisher: University of Hawaii at Manoa
Abstract: Far infrared studies of several salts of tri-n-octylamine have been conducted. Spectra were obtained for these salts in the solid state as well as in carbon tetrachloride and chloroform solutions. Two absorption bands were observed in the 100 cm-1 range. On the basis of a definite anion effect and the large degree of independence of these bands on the degree of aggregation, they were assigned to the stretching modes of the basic ion-pair. To explain the presence of two absorption bands it was proposed that besides the non-aliphatic hydrogen-bond between the cation and the anion these salts may also possess a cation-anion hy­ drogen-bond involving the lambda-methyl hydrogens.
Pages/Duration: vi, 49 pages
URI/DOI: http://hdl.handle.net/10125/32161
Rights: All UHM Honors Projects are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
Appears in Collections:Honors Projects for Chemistry



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