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The Extraction and Solvation of HFeCl4 from 8.15 M Aqueous HCl by 1,2-Dichoroethane Solutions of Bis(2-Chloroethyl_ Ether

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Title: The Extraction and Solvation of HFeCl4 from 8.15 M Aqueous HCl by 1,2-Dichoroethane Solutions of Bis(2-Chloroethyl_ Ether
Authors: Liu, Don
Advisor: McDonald, Ray
Issue Date: 15 Jan 2014
Publisher: University of Hawaii at Manoa
Abstract: The distrihution of HFeCl4 between 8.15 M aqueous HCl 2nd bis(2-chloroethyl) ether in 1,2-dichloroethane was studied as a function of metal and extractant concen¬≠tration. The bis(2-chloroethyl) ether solvation number for the extracted, dissociated ion pair was found to be three at low ether concentrations and five at higher ether concentrations. Results also indicate that 1.6 ether molecules are gained upon dissociation of the extracted jon pair. The disso0iation constant of the extracted bomplex metal acid was found to be 8 x lo-3 in the bis(2-chloroethyl) ether.
Pages/Duration: iii, 68 pages
URI/DOI: http://hdl.handle.net/10125/32146
Rights: All UHM Honors Projects are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
Appears in Collections:Honors Projects for Chemistry



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