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New nickel complexes for trifluoromethylation studies
|Ichioka_Hiromi_r.pdf||Version for non-UH users. Copying/Printing is not permitted||3.23 MB||Adobe PDF||View/Open|
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|Title:||New nickel complexes for trifluoromethylation studies|
|Issue Date:||Dec 2012|
|Publisher:||[Honolulu] : [University of Hawaii at Manoa], [December 2012]|
|Abstract:||We decided to prepare bis-perfluoroalkyl nickel complexes bearing a bipyridine ligand for investigation of the fundamental nickel perfluoroalkyl chemistry and reductive elimination of perfluoroethylene. Moreover, we envisioned a new precursor for investigation of Ar-CF3 reductive elimination. We have successfully demonstrated the syntheses of [(dtbpy)Ni(CF3)2] and [(dtbpy)Ni(CF2CF3)2] in moderate yields. The key intermediate nickel complex, [(tmeda)Ni(CF3)Br] allowed for the preparation of new complexes in good yields.|
|Description:||M.S. University of Hawaii at Manoa 2012.|
Includes bibliographical references.
|Appears in Collections:||M.S. - Chemistry|
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