Please use this identifier to cite or link to this item: http://hdl.handle.net/10125/100562

Hydrogen storage capacity of tetrahydrofuran and tetra-n-butylammonium bromide hydrates at favorable thermodynamic conditions

File Description SizeFormat 
Weissman_Joshua_r.pdfVersion for non-UH users. Copying/Printing is not permitted7.13 MBAdobe PDFView/Open
Weissman_Joshua_uh.pdfVersion for UH users7.2 MBAdobe PDFView/Open

Item Summary

Title: Hydrogen storage capacity of tetrahydrofuran and tetra-n-butylammonium bromide hydrates at favorable thermodynamic conditions
Authors: Weissman, Joshua Tyler Ramos
Keywords: hydrogen storage capacity
tetrahydrofuran
tetra-n-butylammonium bromide
hydrates
Issue Date: Aug 2014
Publisher: [Honolulu] : [University of Hawaii at Manoa], [August 2014]
Abstract: An exploratory investigation was conducted to evaluate the feasibility of employing binary hydrates as a medium for H2 storage. Two reagents, tetrahydrofuran, (THF) and tetra-n-butylammonium bromide (TBAB), which had been reported previously to have potential to form binary hydrates with H2 at favorable conditions (i.e., low pressures and high temperatures), were investigated.
A scale-up facility was employed to quantify the hydrogen storage capacity of THF binary hydrate. Gas chromatograph (GC) and pressure drop analyses indicated that the weight percentages of H2 in hydrate were less than 0.1%. This is well below the current USDOE target of 5.5 wt. % for transportation applications.
To summarize, the major conclusions of this investigation are: H2 can be stored in binary hydrates at relatively modest pressures and temperatures which are probably feasible for transportation applications.
The storage capacity of H2 in binary hydrate formed from aqueous solutions of THF over a concentration range extending from 2.78 to 8.34 mol % and at temperatures above 263 K and pressures below 11 MPa was < 0.1 wt. %.
Under-saturated solutions of THF appeared to have the highest H2 storage capacity.
Description: M.S. University of Hawaii at Manoa 2014.
Includes bibliographical references.
URI/DOI: http://hdl.handle.net/10125/100562
Rights: All UHM dissertations and theses are protected by copyright. They may be viewed from this source for any purpose, but reproduction or distribution in any format is prohibited without written permission from the copyright owner.
Appears in Collections:M.S. - Mechanical Engineering



Items in ScholarSpace are protected by copyright, with all rights reserved, unless otherwise indicated.